Three-component metal-free arylation of isocyanides.
نویسندگان
چکیده
Though the efficiency of isocyanides as strong ligands for transition metals was recognized very early, the disclosure of metal-catalyzed arylation of isocyanides has only been explored quite recently. In most of these studies, the formation of a metal/aryl complex starting from aryl iodide or bromide is followed by isocyanide insertion and trapping of the metal/imidoyl complex with various nucleophiles (Scheme 1). These three-component couplings are mostly
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ورودعنوان ژورنال:
- Angewandte Chemie
دوره 52 28 شماره
صفحات -
تاریخ انتشار 2013